Charles J.R. Hedgecock
Kinetic resolution of the chiral iron acetyl [Fe(η5-C5H5)(CO)(PPh3)COMe]
Hedgecock, Charles J.R.; Prime, Jeremy C.; Case-Green, Stephen C.; Costello, James F.; Davies, Stephen G.; Hedgecock, Charles J. R.; Heaton, Nicholas; Primes, Jeremy C.
Authors
Jeremy C. Prime
Stephen C. Case-Green
James Costello James.Costello@uwe.ac.uk
Senior Lecturer
Stephen G. Davies
Charles J. R. Hedgecock
Nicholas Heaton
Jeremy C. Primes
Abstract
The chiral discrimination displayed between the enolate derived from (RS)-[Fe(η5-C5H5)(CO)(PPh3)COMe] and (1R)-(+)-camphor furnishes a practical route to homochiral (R)-[Fe(η5-C5H5)(CO)(PPh3)COMe] via a kinetic resolution protocol, while a retro-aldol reaction of the diastereoisomerically pure aldol addition product of this kinetic resolution sequence provides a complementary route to the opposite enantiomer (S)-[Fe(η5-C5H5)(CO)(PPh3)COMe].
Citation
Prime, J. C., Hedgecock, C. J., Case-Green, S. C., Costello, J. F., Davies, S. G., Heaton, N., …Primes, J. C. (1993). Kinetic resolution of the chiral iron acetyl [Fe(η5-C5H5)(CO)(PPh3)COMe]. Journal of the Chemical Society, Chemical Communications, 21(21), 1621-1622. https://doi.org/10.1039/C39930001621
Journal Article Type | Article |
---|---|
Publication Date | Dec 1, 1993 |
Journal | Journal of the Chemical Society, Chemical Communications |
Print ISSN | 0022-4936 |
Publisher | Royal Society of Chemistry |
Peer Reviewed | Peer Reviewed |
Volume | 21 |
Issue | 21 |
Pages | 1621-1622 |
DOI | https://doi.org/10.1039/C39930001621 |
Keywords | kinetic resolution, chiral iron acetyl |
Public URL | https://uwe-repository.worktribe.com/output/1109509 |
Publisher URL | http://dx.doi.org/10.1039/C39930001621 |
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